Non-linear Effects in Asymmetric Catalysis: Whys and Wherefores

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Non-linear Effects in Asymmetric Catalysis: Whys and Wherefores

It is argued that the titled non-linear effects (NLE) may arise whenever the order of the reaction in the chiral catalyst in greater than 1. In a fundamental departure from previous approaches, this is mathematically elaborated for the second order case. (NLE may also be observed if the chiral catalyst forms non-reacting dimers in a competing equilibrium; practically, however, this implies the ...

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ژورنال

عنوان ژورنال: Nature Precedings

سال: 2012

ISSN: 1756-0357

DOI: 10.1038/npre.2012.6947.1